有機反應機理的書寫藝術

定　價：￥80.00

作　者：	（美）格羅斯曼編著
出版社：	科學出版社
叢編項：
標　簽：	有機化學

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ISBN：	9787030333018	出版時間：	2012-01-01	包裝：	平裝
開本：	16開	頁數(shù)：	355	字數(shù)：

內容簡介

　　每一個滿懷抱負的有機化學家都嘗試寫出合理的有機反應機理，然而市面上的有關機理正確書寫的書籍卻寥寥無幾?！秶饣瘜W經典教材系列（影印版）：有機反應機理的書寫藝術（原著第2版）》將幫助學生和科研人員提高這一重要技能。《國外化學經典教材系列（影印版）：有機反應機理的書寫藝術（原著第2版）》的突出特點體現(xiàn)在：正確的書寫形式，“常見錯誤提示”，配以大量的難度適宜的問題。其另一個特色是包含過渡金屬參與或催化的反應章節(jié)。相對新的課題，例如，烯烴復分解反應、芳香環(huán)化反應等在《國外化學經典教材系列（影印版）：有機反應機理的書寫藝術（原著第2版）》中均有所涉及。全新修訂的第2版精彩呈現(xiàn)：更新的反應機理，芳香性的討論，酸性，立體化學的拓展，重新組織了自由基反應和金屬參與或催化的反應等內容，增加了新的問題。

作者簡介

暫缺《有機反應機理的書寫藝術》作者簡介

圖書目錄

Preface to the Student
Preface to the Instructor
1 The Basics
1.1 Structure and Stability of Organic Compounds
1.1.1 Conventions of Drawing Structures；Grossman’S Rule
1.1.2 Lewis Structures；Resonance Structures
1.1.3 Molecular Shape；Hybridization
1.1.4 Aromaticity
1.2 BrCnsted Acidity and Basicity
1.2.1 PK Values
1.2.2 Tautomerism
1.3 Kinetics and Thermodynamics
1.4 Getting Started in Drawing a Mechanism
1.5 Classes of Overall Transformations
1.6 Classes of Mechanisms
1.6.1 Polar Mechanisms
1.6.2 Free.Radical Mechanisms
1.6.3 Pericyclic Mechanisms
1.6.4 Transition-Metal-Catalyzed and-Mediated Mechanisms
1.7 Summary
Problems
2 Polar Reactions under Basic Conditions
2.1 Substitution and Elimination at C（sp3）一X Bonds.Part I
2.1.1 Substitution by the SN2 Mechanism
2.1.2 Elimination by the E2 and Elcb Mechanisms
2.1.3 Predicting Substitution VS.Elimination
2.2 Addition of Nucleophiles to Electrophilic仃Bonds
2.2.1 Addition to Carbonyl Compounds
2.2.2 Conjugate Addition；The Michael Reaction
2.3 Substitution at C（sp2）一X Bouds
2.3.1 Substitution at Carbonyl C
2.3.2 Substitution at Alkenyl and Aryl C
2.3.3 Metal Insertion；Halogen-Metal Exchange
2.4 Substitution and Elimination at C（sp3）-X Bonds，Part II
2.4.1 Substitution by the SRNl Mechanism
2.4.2 Substitution by the Elimination-Addition Mechanism
2.4.3 Substitution by the One-Electron Transfer Mechanism
2.4.4 Metal Insertion；Halogen一Metal Exchange
2.4.5 Ol-Elimination；Generation and Reactions of Carbenes
2.5 Base-Promoted Rearrangements
2.5.1 Migration from C to C
2.5.2 Migration from C to O or N
2.5.3 Migration from B to C or O
2.6 Two Multistep Reactions
2.6.1 The Swem Oxidation
2.6.2 The Mitsunobu Reaction
2.7 Summary
Problems
3 Polar Reactions Under Acidic Conditions
3.1 Carbocations
3.1.1 CarbOCation Stability
3.1.2 Carbocation Generation；The Role of Protonation
3.1.3 Typical Reactions of Carbocations；Rearrangements
3.2 Substitution and 一Elimination Reactions at C（sp3）一X
3.2.1 Substitution by the SNl and SN2 Mechanisms
3.2.2 Elimination by the E1 Mechanism
3.2.3 Predicting Substitution VS.Elimination
3.3 Electrophilic Addition to Nucleophilic C=C Bonds
3.4 Substitution atNucleophilic C=C Bonds
3.4.1 Electrophilic Aromatic Substitution
3.4.2 Aromatic Substitution of Anilines via Diazonium Salts
3.4.3 Electrophilic Aliphatic Substitution
3.5 Nucleophilic Addition to and Substitution at Electrophilic Bonds
3.5.1 Heteroatom Nucleophiles
3.5.2 Carbon Nucleophiles
3.6 Summary
Problems
4 Pericyclic Reactions
4.1 Introduction
4.1.1 Classes of Pericyclic Reactions
4.1.2 Polyene MOs
……
5 Free.Radical Reactions
6 Transition-Metal-Mediated and-Cata！vzed Reactions
7 Mixed.Mechanism Probiems
A F.nal Word
Index